Wearing hard hats and armed with buckets and cloths, the four specialist technicians are descending the London landmark by rope to clean and inspect the four clock faces.
The clock faces on the Elizabeth Tower were last cleaned in 2010 and besides getting rid of any dirt that has accumulated since then, the experts are conducting a photographic survey to check the dials for damage.
"Big Ben is one of the UK's greatest icons, and cleaning the Great Clock is a vital part of its maintenance," said Steve Jaggs, deputy keeper of the clock.
Each clock face is made up of 312 pieces of white opaque glass, held together by a cast iron framework.
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The clock inside the tower continues to keep time during the cleaning process but the hands on the face being washed are set at 12 to make it easier for the technicians to clamber around.
Five days have been set aside for the job -- one for each of the four clock faces, with a contingency day in case the weather makes it too risky to work.
The tower was constructed as part of the reconstruction of the Houses of Parliament by architects Charles Barry and Augustus Pugin following a major fire in 1843.
There are two theories of how the bell came to be known as Big Ben.
The most likely explanation is that it was named after Benjamin Hall, the engineer whose name is inscribed on the bell, but some believe it is named after Ben Caunt, a champion heavyweight boxer of the 1850s.