The incident took place at Fofnarkhurd village near here last night.
Relatives of Dilip Jaikar, who consumed pesticide kept in a bottle in his home, rushed him to district hospital where doctors pronounced him brought dead, Shahpur Police Station Sub-Inspector (SI) Devishanker Singh Bisen said.
Jaikar was in an intoxicated state when he gulped the pesticide thinking it was liquor, he said.
Jaikar's wife left him a month ago and started living with her parents at Jalgaon in neighbouring Maharashtra following a marital discord. Since then, Jaikar had been living in dejection and drinking heavily, he added.