The incident occurred at Atkula village last night when Tarun Fulmali, who owns a small car repairing unit, allegedly threw acid on his wife Manjushri's face suspecting that she was having an illicit relation with a villager, they said.
Officer-in-charge of Nalhati police station, Somnath Bhattacharya, said 35-year-old Manjushri lodged an FIR blaming her husband for the incident.
Tarun, who surrendered before the police this morning apparently to save himself from being assaulted by local people, denied that he had thrown acid on his wife.
The couple have two sons and a daughter.