The accused, identified as Rajesh Rawal alias Raju Marwadi, was picked up by officials of Amboli police station, said a senior officer.
According to police, Marwadi is wanted under Arms Act, besides two cases of murders and other crimes in Gujarat.
The official said the police suspect Marwadi's involvement in a high-profile murder case in Ahmedabad, but did not elaborate further.
The accused will be handed over to Gujarat police, he said.