The singers are hitting the road with the UNIDO2, a play on the word "United", and performing in cities throughout the US and Canada, reported Billboard magazine.
The duo will kick off the trek on September 11 in Anthony's native Puerto Rico.
Anthony, 46, and Vives are continuing their success from the hit single Cuando Nos Volvamos a Encontrar (When We Meet Again), which won the Latin Grammy Award for Best Tropical Song last year (14), and also earned nominations for Record and Song of the Year.