After seeing championship leader Briton Lewis Hamilton and his team-mate German Nico Rosberg beaten off the grid for the second race in succession in Sunday's Hungarian Grand Prix, the Austrian boss knows they are under pressure.
"We got jumped by two Williams' last time and jumped by the two Ferraris this time," he said, referring to the British Grand Prix and Sunday's contest at the Hungaroring won by four-time champion German Sebastian Vettel for Ferrari.
Vettel and his Ferrari team-mate Finn Kimi Raikkonen surged past both Hamilton and Rosberg at the start of Sunday's 69-laps race, the German to claim an emotional triumph he dedicated to colleague Frenchman Jules Bianchi, who died on July 17.
Raikkonen followed him in second place for much of the race before power unit problems forced him into retirement, gifting second and third places to the revived Red Bull duo of Russian Daniil Kvyat and Daniel Ricciardo after both Rosberg and Hamilton had suffered more lost positions following collisions with the Australian driver.
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"I am very concerned about this," said Wolff. "It is various issues. And it is very difficult to get the calibration right. We had two very good practice starts off the line and then, when it mattered, on the actual race start, we had too much wheel spin.
"Then, when that happens, you get overtaken in a way you cannot recover from..."
But in what is becoming a worryingly bad habit, he was passed at the start and left with a recovery mission that, on Sunday, turned into a series of mishaps, errors, accidents and penalties.
Hamilton apologised for his driving, saying it was "a bad day at the office" and entirely his fault, while Rosberg threw away a podium finish when he suffered a puncture in a collision with Ricciardo in the closing laps, finishing eighth.
He is the only man to have broken Mercedes stranglehold which was so weakened on Sunday that they did not have a driver on the podium for the first time this year.