Rane, however, said he would continue in the Congress.
A former Shiv Sena chief minister, Rane was said to be lobbying hard to ensure Chavan's exit but apparently decided to quit as minister as the party high command appeared in no mood to heed his demand.
Resigning for a second time since the party's rout in the Lok Sabha polls, Rane called on Chief Minister Chavan at his official residence and submitted his resignation, which is yet to be accepted.
He said his supporters were not made MLCs, given ministerial positions or made heads of the state-owned corporations or boards.
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Rane also lashed out at Chavan, saying, "Victory in upcoming assembly elections under the Chief Minister's leadership is difficult. He has a clean image but decision- making is slow, implementation of decisions already taken is tardy. This affects the people who made known their displeasure with the government in Lok Sabha polls.
Though Rane, an influential leader in the Konkan region, claimed Chavan told him he would apprise Congress president Sonia Gandhi of the development and revert to him, the Chief Minister said there was no need to discuss the resignation with party leadership.
"I will go through his genuine and concrete grievances and take a decision accordingly," Chavan told PTI.