The clip purportedly shows Shinde urinating by the roadside on the Solapur-Barshi road when he was travelling in his car.
Shinde had said that he was unwell after spending nearly a month touring the state for the government's flagship Jalyukta Shivar scheme and had to relieve himself in the open as he couldn't find a toilet while travelling.
Taunting the minister, Congress spokesperson Sachin Sawant said Shinde proved on World Toilet Day yesterday that Maharashtra has become open defecation free.
He accused the government of patting its back on "non-existing development".
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"Earlier, Urban Development department had shown a photo of Bangkok to showcase development. Then it went on to claim how villages, which were not even included in the Jalyukt Shivar scheme, had benefitted from it," he said.
Citing the figures obtained from the RTI, Sawant said the government created only 1,624 toilets in Mumbai in the last three years and that many people still defecate in the open in the megalopolis.