Just before the proceedings began, Modi, External Affairs Minister Sushma Swaraj and Parliamentary Affairs Minister Ananth Kumar greeted leaders from various parties in the opposition benches including Congress president Sonia Gandhi, Samajwadi Party leader Mulayam Singh Yadav and National Conference leader Farooq Abdullah.
Abdullah took oath as Lok Sabha member today after winning the Srinagar bypoll recently.
Swaraj, who greeted the opposition leaders after Modi, was seen talking to Congress leader in the Lok Sabha Mallikarjun Kharge.
Earlier this morning, Modi had said that like the monsoon, this session also brings a spirit of hope.
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"After the summer, the rains fill the soil with pleasant smell. The same way, due to the good rains of the GST, the whole session will be full of enthusiasm," he told reporters.
The results will be declared on July 20 in New Delhi.
The BJP has exuded confidence that Kovind would win with a "comfortable" margin, while the opposition said Kumar was the best choice in the "clash of ideologies".