Speaking at the UP Investor Summit here, he said the investment will be over and above the Rs 20,000 crore Jio has already invested in the state in rolling out high-speed 4G telecom venture.
Ambani said India cannot rise to its full potential without the rise of 22 crore people of Uttar Pradesh.
He also vowed full support to the 'Namami Gange' project.
"I have a commitment.... the Clean Ganga Mission is gathering momentum ...we at Reliance Foundation would deem it as our pious duty to contribute to the success of this mission and are ready to execute whatever part of the project is assigned to us," he said in the presence of Prime Minister Narendra Modi.
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The RIL chief said he wanted every youth in the state to be a smart youth and for this Jio will make available over 2 crore phones in the state in the next two months on a priority basis.
"Jio has already created over 40 thousand direct and indirect jobs in UP. Along with other businesses of RIL , Jio will create over one lakh new and sustainable livelihood opportunities in the next three years," Ambani said.