The death of Kim, the estranged half brother of North Korea's ruler, has unleashed a diplomatic battle between Malaysia and North Korea.
The autopsy is especially sensitive because North Korea had asked Malaysia not to perform one, but authorities carried it out anyway, saying they were following the law.
Also today, amid growing fallout from the killing, Malaysia announced it is scrapping visa-free entry for North Koreans.
The women, who were caught on grainy surveillance video, have been charged with murder. Both say they were duped into thinking they were playing a harmless prank and did not know they were handling a lethal toxin.
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Malaysia's autopsy finding that VX nerve agent killed Kim boosted speculation that North Korea orchestrated the attack. Experts say the oily poison was almost certainly produced in a sophisticated state weapons laboratory.
Ri said Kim had a history of heart problems and had been hospitalised in the past. He said he understood that Malaysian officials found medication for diabetes, heart problems and high blood pressure in Kim's belongings and concluded he wasn't fit to travel.
"This is a strong indication that the cause of death is a heart attack," Ri said.
North Korea does not acknowledge that it was Kim Jong Nam who died. Instead, it refers to the victim as Kim Chol, the name on the diplomatic passport he was carrying. Malaysia has confirmed that the victim was Kim Jong Nam.
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