Campbell, 46, will play Rose Spencer, a beautiful and wealthy London-er, reported Deadline.
Other cast members include Queen Latifah, Benjamin Bratt, and newcomers Jude Demorest, Ryan Destiny, Brittany O'Grady, and Amiyah Scott. Lenny Kravitz will also make a guest appearance on the show.
"Star" is created and produced by Daniels and Tom Donaghy, other executive producers include Pamela Oas and Effie Brown.