Dominica-born lawyer Patricia Scotland, who was appointed the Commonwealth's first female secretary-general on Friday, told AFP she would harness the international family's "huge convening power".
Among her top priorities: "Action to combat any form of abuse against women".
"One in three women in our world suffer from domestic violence. It's the greatest cause of morbidity between women and girls," she said, adding that there was "a lot of work to do".
"Forced marriage, female genital mutilation, child abduction... These issues affect all of us," said the 60-year-old, who will take over the reins from Indian diplomat Kamalesh Sharma in April 2016.
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A forum on women was included at the summit for the first time this year, but the failure for LGBT rights to get any serious floor time enraged activists -- particularly as consensual homosexual activity is still only legal in 13 of the groups 53 countries, according to the Human Dignity Trust.
The baroness admitted that "there are lots of things we could do better".
But although the organisation can never be forced to do anything, because it works by consensus, she insisted it "has never been more relevant than it is right now".
"I think most of us are looking for vehicles where we can come together in partnership to try and hone the sort of solutions that the world absolutely needs today," she said, adding that "if we choose, we could come together and do something quite extraordinary".
The Commonwealth's potential can be seen in its work to eradicate polio, she said.
Leaders from Britain, Canada, Malta, Nigeria and Pakistan called this weekend for a push to ensure the disease is wiped off the face of the planet by the end of 2016.
"It will only be the second time in the history of humanity that we've been able to eradicate a disease. If we can do that with polio, we can do that with other things too," she said.