The individuals all come from the top echelon of the state security apparatus that was responsible for cracking down on anti-government protests that rocked Venezuela last year and for pursuing charges against leading opponents.
"Corrupt actions by Venezuelan government officials deprive Venezuela of needed economic resources that could be invested in the Venezuelan people and used to spur economic growth," Treasury Secretary Jacob Lew said in a statement.
"These actions also undermine the public trust in democratic institutions and the human rights to which Venezuelan citizens are entitled."
President Nicolas Maduro railed against the sanctions Tuesday night in a speech that all Venezuelan radio and television stations were required to carry. The embattled president denounces the Yankee empire almost nightly on national television, but yesterday he took an unusually furious tone, saying the sanctions were further proof that the US is determined to topple his administration and seize control of Venezuela.
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He vowed that US meddling would have no effect on his government.
"Obama's time will end, and the revolution will continue," he said.
Diosdado Cabello, the powerful head of Venezuela's National Assembly, said Maduro would personally denounce the US actions when he, Obama and regional leaders travel to Panama next month to attend the Summit of the Americas.