Brent North Sea crude for delivery in April rocketed USD 2.77 to stand at USD 111.84 a barrel in London midday deals.
New York's main contract, West Texas Intermediate (WTI) for April, jumped USD 1.94 to USD 104.53 a barrel.
Ukraine accused Russia today of pouring extra troops and military planes into Crimea, a predominantly Russian-speaking peninsula in the southeast of the former Soviet state.
Crimea has been under de facto occupation by pro-Kremlin troops since President Vladimir Putin won parliament's authorisation Saturday to use force in Ukraine.
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"Russia is the world's biggest oil producing country, so any political uncertainty could raise serious concerns about oil supplies issues worldwide."
Desmond Chua, an analyst at CMC Markets in Singapore, said that the escalating tension in Ukraine was providing strong support for oil prices.
"Considering that Ukraine is part of the supply chain for Brent, we are looking at this pent-up risk premium resulting in overshooting prices," Chua told AFP.
JP Morgan Commodities Research analysts noted that although Ukraine is neither a major oil producer nor oil consumer, it is an important transit country for Russian energy exports.
More than 70 per cent of Russia's gas and oil flows to Europe pass through its territory. In turn, Europe is the buyer for nearly 90 percent of Russia's oil exports.