Sources in Delhi said that Pravash Ranjan Samal, a bio-medical engineer hailing from Odisha, escaped from his captors and conveyed to one of his friends that he was fine.
Samal(48) and Ramamurthy Kosanam, a resident of Andhra Pradesh, were abducted reportedly a few days ago from Ibn-e-Sina in Sirte where they were working.
The sources said efforts are on to secure the release of Kosanam who was reported to be safe.
In Odisha, family members of Samal said they received a call from him today and were told he has been "released."
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Samal hails from Bhagabanpur area in Kendrapara town.
The family members said they received the call from Samal at around 2.25 PM today.
"I was told by a friend yesterday evening about my elder brother's disappearance from his workplace in Libya. It was a bolt from the blue for us. He has been serving in Libya since 2000. During Libyan civil war in 2011 year, he stayed there safely.
The state administration was maintaining constant touch with the higher-ups and the Samal family.
"All of us hope that Pravas returns unharmed," Kendrapara Collector Debraj Senapati said.
In July, four Indian teachers were kidnapped in Libya allegedly by the Islamic terrorists and release of two of was secured by the government.
The two other nationals remain in the custody of Islamic militants for past more than one-and-a-half months.
They identified the teachers still in captivity as T Gopikrishna and Ch Balram, both of whom hail from Hyderabad.
According to the officials, top officials at the Indian Embassy in Libya were contacted today, who have said that the trio were safe.