Bopanna and his Romanian partner Florin Mergea, seeded sixth, open their campaign against Croatian pair of Marin Draganja and Nikola Mektic.
Paes and Polish teammate Marcin Matkowski are up against Taipei's Yen-Hsun Lu and Serbia's Janko Tipsarevic.
Paes and Bopanna are the only Indians competing in the men's events at the grass court Grand Slam as Ramkumar Ramanathan and Saketh Myneni had lost in the singles qualifiers while the pair of Purav Raja and Divij Sharan had lost in the doubles qualifying event.