A ship chartered by Manila is set to sail from Malta in the coming days to pick up Filipinos from the ports of Benghazi, Misrata and possibly Tripoli, a foreign department statement said.
However, the government has expressed frustration at the reluctance of many of the 13,000 workers to leave due to concerns they would not find jobs at home.
"The (Department of Foreign Affairs) is appealing with urgency to those who have not made the decision to be repatriated to please consider doing so as the avenues of repatriation are quickly diminishing," the statement said.
He said the Tunisia-Libya border crossing was closed yesterday following a shooting incident, while a border crossing to Egypt has been closed for months.
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Philippine officials have said ships would be able to carry about 1,500 people at a time.
The Philippines warned Filipinos to leave Libya on May 30.
It then decided on a mandatory evacuation order last month following the beheading of a Filipino construction worker in Benghazi.
A Filipina nurse was also abducted and gang-raped in Tripoli on Wednesday.
More than 200 others are being processed to be repatriated from Tripoli, it said, adding "this number is rapidly increasing".
Del Rosario spoke to a group of 95 Filipinos awaiting flights home from Tunisia and urged them to "convince their friends and co-workers who are still in Libya" to leave now, it added.
The Philippines previously evacuated its workers in Libya in 2011 during the violent chaos leading to the toppling of the late dictator Moamer Kadhafi.
However, about 1,600 Filipinos, mostly doctors and nurses, elected to stay throughout that upheaval.
About 10 million Filipinos work around the world, earning more money in a wide range of skilled and unskilled sectors than they could in their struggling homeland.