The 38-year-old actress and Pitt, 50 -- who are parents to three adopted kids Maddox, Pax, Zahara, and three biological children, Shiloh, Knox, and Vivienne -- surprised everyone with
their costume at the award ceremony held last night, reported Ace Showbiz.
Jolie looked chic as she completed her look with a white shirt, black pants, shoes and jewellery. The actress styled her hair loose and wore natural make up.
Pitt wore Valentino outfit.
Pop diva Madonna and son David Banda also wore matching suits to the Grammy Awards last month.