Polling began at 7 am and will conclude at 6 pm. Counting of votes will be held on October 19, poll officials said. The elections will elect members of the 13th Assembly in the state.
Prominent candidates in the poll arena include former deputy CM Ajit Pawar and former ministers R R Patil and Chhagan Bhujbal of NCP, Devendra Fadnavis, Eknath Khadse, Vinod Tawde and Pankaja Munde of BJP, Subhash Desai, Suresh Jain and Deepak Kesarkar of Shiv Sena, former ministers Patangrao Kadam, Shivajirao Moghe and Rajendra Darda Congress and Bala Nandgaonkar of MNS.
There are 83 constituencies having more than 15 candidates and a constituency where there are more than 32 candidates.
Out of the total 8,35,38,114 voters, 4,40,26,401 are men and 3,93,63,011 are women. There are 984 voters in the "others" category. The number of service voters is 1,47,718.
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Registered parties other than recognised state and national parties have fielded 761 candidates. Also, there are 1,699 independents candidates in the fray.
Chinchwad in Pune district, with 4,84,080 voters, is the largest constituency, while Wadala in Mumbai, with 1,96,859 voters is the smallest.
The Election Commission has deputed 135 general observers, 112 expenditure observers, five police observers and 18 awareness observers, the officials said.
Altogether 5,84,617 polling personnel have been deployed. The number of polling stations is 91,376.