A former manager with the Benfica Reserve side, De Matos replaces Nicolai Adam, who was forced to resign under controversial circumstances after a revolt from the players.
De Matos had earlier met the AIFF Advisory Committee comprising former India captains Bhaichung Bhutia and IM Vijayan apart from Sports Authority of India (SAI) DG Injeti Srinivas for a round of interviews.
He also met AIFF president Praful Patel in Mumbai yesterday for a final round before the parent body zeroed in on him. He has had five appearances for the Portugal national side.
The 63-year-old coach thanked AIFF for making him a "part of the project."
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"My role will be to orchestrate everything wherein the players will be playing their part," he told the AIFF Committee.
"I admire AIFF's vision and the U-17 World Cup will act as a base for development of Football in India. The players need to believe in themselves to do something special for the Country," he stated.
"I will retain the positives of the last two years as we move forward," he maintained.
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