Mukherjee is likely to raise the issues of China blocking India's bid to get a UN ban on JeM chief Masood Azhar and its stand that New Delhi must sign the Nuclear Non-Proliferation Treaty to get membership of the elite Nuclear Suppliers Group (NSG). The lingering boundary issue may also figure in talks.
This will be the first visit of Mukherjee to China as President though he had visited the country a number of times in different capacities. The last Presidential visit to China was by Pratibha Patil in 2010.
Ties between the two countries have been on an upswing since Xi's landmark India visit in September, 2014 during which both countries had signed 12 agreements and China pledged an investment of USD 20 bn in India's infrastructure sector.
Prime Minister Narendra Modi had visited China in May last year during which both sides had resolved to further deepen ties in a range of areas.
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The comments came against the backdrop of Beijing blocking India's bid to put Azhar on the UN list of proscribed terrorists.
Mukherjee will begin his visit by arriving in the highly industrialised Chinese city of Guangzhou tomorrow. The city which has strong business links with India has an economy of over USD 1 trillion.
Besides interacting with the Indian community, which has over 3,000 businessmen, Mukherjee will also addressIndia- China Business Forum to highlight the investment opportunities in India.
There, the President will have meetings with the Governor who is also the party secretary and attend a lunch for him in his honour.
On the second leg of the visit, he will travel to Beijing where he will hold wide-ranging talks with the Chinese leadership on key bilateral, regional and global issues.
A key engagement of the President will be a roundtable of Vice Chancellors of Chinese and Indian universities. A number of MoUs will be signed between academic institutions of both the countries.
Mukherjee will be accompanied by a delegation of academicians including Vice Chancellors of two central universities as well as heads of IIT- Delhi and Bhubaneshwar, IIM, Ahmedabad and NIT Nagpur and Agartala.
Union Minister Santosh Ganwar and four MPs will also accompany the President as part of the delegation.