At the Sir Vivian Richards Stadium, Rajendra Chandrika (22) and Marlon Samuels (39) put on 55 runs for the third wicket before the morning session was cut short by rain and early lunch taken.
The morning began with overnight batsmen Chandrika and Darren Bravo (10) looking to play on for time as well as score runs whenever possible. India started the proceedings with Ishant Sharma (1-17) and Umesh Yadav (1-19), the duo looking sharp and bowling fuller deliveries, especially the former who was a marked improvement from his first innings' outing.
Samuels in particular looked aggressive and used good hand-eye co-ordination to smack nine boundaries in the session. The two batsmen put on 50 off 98 balls, while the West Indies' score crossed the 50-mark in the 27th over.
Mohammed Shami (0-20) was soon introduced into the attack, and he was on the money straightaway.
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R Ashwin (0-20) was the other bowler used in this session, even as Murali Vijay stayed away from the field for a third consecutive day as a precaution. He had been hit on his thumb when fending off Shannon Gabriel on the first morning.
Yesterday, Mohammed Shami and Umesh Yadav shared eight wickets to bowl the hosts out for 243 runs and enforce the follow-on thereafter.
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Rahul struck one six and seven fours in his confident knock.
Earlier in the morning, it took Ashwin just five balls to dismiss the last Australian wicket when he induced a wild shot from Starc only to be holed out to deep mid-wicket.
Starc, who unbeaten on 57 off 58 balls overnight in a team total of 256 for nine, departed for 61 off 63 balls, and his pulverizing knock included three sixes and six fours.
With Starc's scalp, Ashwin also went past the great Kapil Dev's record most Test wickets in a home season.
While Ashwin ended up with three victims, Umesh Yadav was the best bowler for India with superb figures of 4 or 32, his best figures at home and second-best overall after the 5 for 93 he took against the same opponents in Perth in January 2012 on his debut.
However, the Indians' delight at ending the Australian innings, which had unexpectedly bloomed bigger from a struggling 205 for nine due to Starc's counter-hitting last evening, was nipped in the bud when they lost three of their top scoring batsmen, including captain Kohli, within the first 15 overs.