Resuming at overnight 249/5, Khan's 203-ball 110 was instrumental in steering Rajasthan to the formidable total in 105.4 overs. Khan struck 15 fours in his knock.
For Odisha, Govind Poddar and Suryakant Pradhan picked up three wickets apiece.
In reply, Odisha endured a top-order collapse that left them at 64/5 at one stage. Deepak Behera's unbeaten 49 off 85 balls was the lone noteworthy contribution in Odisha's disastrous scorecard.
Brief Scores:
Rajasthan: 323 in 105.4 overs (S F Khan 110, Suryakant Pradhan 3/97).
Odisha: 143/8 in 45 overs (Deepak Behera 49 not out, Aniket Choudhary 4/34).
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