Uttar Pradesh dominated the first half of the Pool C game and took a 2-0 lead through a field goal by Amir Khan (10th minute) and penalty corner strike from Diwakar Ram (33rd).
Uttar Pradesh continued its dominance in the second half extended its lead in the 44th minute through Ajit Pandey.
Odisha tried to forge a comeback when Amon Mirash Tirkey pulled one back in the 48th minute to make the scoreline 3-1.
Odisha, in between, managed to score another goal through Joseph Toppo (61st).
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Earlier in the day, Jharkhand beat Hockey Bhopal 3-0 in Pool C.
Birshu Bhengra (57th, 63rd, 68th) scored a hat-trick for Jharkhand.
In another match, Food Corporation of India (FCI) failed lost 0-3 to Railways in a Pool D match.
Railways all three goals came via penalty corner conversions from the sticks of Amit Rohidas (35th, 54th) and M G Poonacha (23rd).
Pool C: Uttar Pradesh 5 Diwakar Ram (33rd, 54th, 64th); Amir Khan (10th); Ajit Pandey (44th) vs Hockey Odisha 2 Amon Mirash Tirkey (48th); Joseph Toppo (61st).
Pool C: Jharkhand 3 Birshu Bhengra (57th, 63rd, 68th) vs Hockey Bhopal 0.
Pool D: Railways Amit Rohidas (35th, 54th) M G Poonacha (23rd) vs Food Corporation of India 0.