The French label revealed Rihanna's glamorous ads which were photographed by Steven Klein in Versailles, reported Hollywood Life.
The campaign also includes a short film called Secret Garden, where the American Oxygen singer is seen wandering around Versailles at night.
Dior has been teasing clips from the short film, which also features Rihanna's new song titled 'Only If For a Night'.
Rihanna has joined Oscar winners Natalie Portman, Charlize Theron and Jennifer Lawrence as the faces of Dior. Lawrence was also recently announced as the face of Dior's beauty collection Addict Lipstick.