The 24-year-old 'We Found Love' hitmaker is expected to perform two songs, one of which will be her new single 'Diamonds' at the event, reported People magazine.
She will be joined on stage by Justin Bieber and Bruno Mars.
Previous musical guests to have performed alongside the models include the Spice Girls, Katy Perry and Justin Timberlake, while last year's Nicki Minaj, Kanye West, Adam Levine and Jay-Z all performed, with Beyonce Knowles looking on from the front row.
Every year, the hugely-anticipated event sees our favourite Victoria's Secret Angels take to the catwalk.
Previous shows have seen everyone from Heidi Klum and Miranda Kerr, to Rosie Huntington-Whiteley, Doutzen Kroes, Candice Swanopoel and Alessandra Ambrosio showcasing the latest fantastical creations from the lingerie brand.