64-year-old Munde, who made his entry into the Union Cabinet for the first time last week, was on his way to the airport when his car was hit by another vehicle at Prithviraj road-Tughlak road roundabout in the heart of the capital.
A brother-in-law of late BJP leader Pramod Mahajan, Munde is survived by his wife and three daughters, one of whom is an MLA from Parli in Maharashtra's Beed district.
"On his arrival at the Trauma Centre, there was no spontaneous breathing, no blood pressure, no pulse, no cardiac activity. So immediately Cardiopulmonary Resuscitation (CPR) was started and continued for the next 15 minutes. Despite resuscitative measures, Munde could not be revived and was declared dead at 7:20 AM," he said.
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The body has been shifted to the mortuary for postmortem. A board has been formulated by the head of forensics to conduct the postmortem.
As it is a medico-legal case, the reason for the death can only be ascertained after postmortem, the doctor said.
Munde's Secretary S Nair, who was in the car, said the Union Minister received a huge shock after the accident and apparently suffered a massive heart attack.