At stake is a place in the semi-finals against Dempo SC. The two sides last met in the finals of the Durand Cup in November when Salgaocar emerged triumphant courtesy a solitary Saran Singh goal.
Pune FC are currently placed third in the group with four points and go into the game knowing that nothing short of a win will be enough to see them through.
Salgaocar went down 2-3 on the opening day to Bengaluru FC, but have since re-grouped and won their last two outings against Shillong Lajong (2-1) and Mohun Bagan (4-1) respectively.
In the last match against Mohun Bagan, after being a down a goal, the Greens put up a spectacular second half display to thump the Kolkata giants.
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Pune FC, on the other hand, started off with a win against Shillong Lajong, but have since managed only a single point from their last two encounters, having drawn against Mohun Bagan and lost to Bengaluru FC.
Salgaocar were backed by a vociferous crowd in their last game and they will hope for a similar turnout when they take on Pune tomorrow.