Although Bullock split from James in 2010 after it was revealed the 'Monster Garage' host had cheated on the 48-year-old actress, he wants her to be among the guests at his forthcoming nuptials.
But his invitation is unlikely to be accepted, reported In Touch magazine.
"It seems Jesse has colossal gall to match his colossal ego. After all of the hurt and humiliation he's caused her, Sandra is the last person on earth who would attend his wedding.
"Since their split he's always trying to reach out but Sandra wants nothing to do with him," said a source.