Douglas Hamilton, with the University of Maryland, and colleagues identified images taken by NASA's infrared sky-mapping WISE telescope and found that the outermost ring, discovered in 2009, contains mostly small particles.
The ring, called the 'Phoebe ring', is believed to contain dust and ice particles ejected from Saturn's outer moon, Phoebe, after micrometeoroid and other impacts, 'Discovery News' reported.
The ring is tilted at an angle of 27 degrees, relative to the other seven known rings, and like Phoebe, orbits Saturn in a backwards, or retrograde, direction.
The new images taken from NASA's WISE probe suggest the ring is over 270 times the radius of Saturn, researchers said.
The Phoebe ring begins about 3.7 million miles away from Saturn and fans out a 'surprisingly' distant 10 million miles, with a vertical expanse of about 1.5 million miles, making it well over 10 times larger than what was previously believed to be Saturn's largest ring, the E ring, researchers said.