Their first meeting is scheduled for February 22 in the Asian Champions League. It will be in Guangzhou, the southern China city just 75 miles (120 kilometers) from Hong Kong, in front of 40,000 fans, but expected to draw eyes from all over the world.
Chan and her Eastern side from Hong Kong will make their league debut against Scolari and his powerhouse Guangzhou Evergrande, a two-time league champion.
"I am happy to meet Scolari," Chan said. "The Asian Champions League is a valuable opportunity for us to learn from opponents like Guangzhou and improve ourselves."
In April, she led Eastern to its first Hong Kong Premier League title in two decades, with a game to spare. That made her the first female to coach a professional men's team to a topflight title. She was named Hong Kong coach of the year and, this month, Asian female coach of the year. Eastern was currently second in the premier league.
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Hong Kong received an automatic entry into the Asian Champions League for the first time, and Eastern drew a tough group: Guangzhou Evergrande, another two-time champ in Suwon Bluewings, and either Urawa Reds, another former champ, or Kawasaki Frontale.
Moya Dodd, vice-president of the Asian Football Confederation and a former Australia women's player, believes Scolari has the most to lose from the matchup with Chan.
"Gender aside, this is a game between one of club football's rising powers, and a team that is less resourced and less fancied," Dodd said. "On the coaches' bench you have a rising star taking on one of football's old masters, a World Cup winner, no less. It's a great story for the fans, and all the pressure will be on Scolari."
"The closer you get to the field, the harder it is for a woman," she said. "It's a positive sign that growing up in the women's game can provide the experience and learning to launch a coaching career in any part of the game, including the Champions League."
Chan graduated from a two-year AFC future coaches program in 2012, worked as a data analyst at Hong Kong Pegasus club, was promoted to the managerial staff, and helped the club's under-18s to win three trophies.
"Chan has a huge following here in Hong Kong," said Mark Sutcliffe, the CEO of the Hong Kong Football Association. "She is an inspiring figure ... And the accolades keep pouring in. She seems to be taking it all in her stride and remains humble and grounded."
Chan just wants to get on with it.
"I have received some awards and attention from the world," she said. "However, it is not important what people say, I just want to stay humble and work hard and learn to be a good coach for my club.
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