The Scottish parliament's vote on Wednesday is widely expected to endorse Sturgeon's campaign to get the British government to agree to a second vote after a 2014 one in which Scots voted to stay in Britain.
The semi-autonomous Scottish government wants to ask the people of Scotland to reconsider their vote against independence with a new referendum before Britain is expected to leave the EU in 2019.
Sturgeon, leader of the ruling Scottish National Party (SNP), intends to use the Edinburgh parliament's voice to assert Scotland's "sovereign right" to choose its own future.
The Scottish parliament cannot hold a legally-binding referendum without London's consent -- and Conservative Prime Minister Theresa May has insisted that "now is not the time" for a vote.
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But Sturgeon has said it would be "democratically indefensible" to block a referendum, although she has signalled she is willing to negotiate on a date.
"This crucial decision over our future should not be made unilaterally by me, or by the Prime Minister," she said.
The SNP does not have an outright majority in Edinburgh, but it has already secured the support of the Green party for another independence bid.
Patrick Harvie, leader of the Greens, said: "I think Theresa May will be taking a huge risk... If she refuses to acknowledge that we have a right in Scotland to have a say about our future."
Scotland voted against independence by 55 percent in 2014, but the campaign left the unionist camp politically divided while nationalists flocked to the SNP in their droves.
The SNP gained twice as many votes as the other parties, and Scotland was indeed outvoted by England and Wales in the Brexit referendum the following month, sparking a fresh constitutional crisis.