The BSE barometer, which opened on a flat note, remained sideways for most part of the session awaiting quarterly GDP numbers, but sank heavily on weak opening in European shares.
Most markets in Asia, including China and Hong Kong, were closed for the Lunar New Year holiday.
"Continuous fall in oil prices and slowdown in China is impacting global markets as well as India. European market has reacted negatively on disinflation concerns," said Vinod Nair, Head-Fundamental Research of Geojit BNP Paribas.
The BSE Sensex resumed higher at 24,637.41 and firmed up further to a high of 24,698.95 on early buying in view of good foreign capital inflows. However, it dropped afterwards to 24,196.84 on fag-end selling pressure on the back of lower European cues, before finishing at 24,287.42, showing a loss of 329.55 points or 1.34 per cent.
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This was the index's biggest single-day fall since January 20. It had gained 393.65 points in the last two sessions.
The NSE 50-share Nifty also moved down by 101.65 points or 1.36 per cent to close at 7,387.25 after moving in a range of 7,512.55 to 7,363.20.
Bhushan Steel surged by up 6.28 per cent, JSW Steel ended 0.99 per cent higher, while Tata Steel gained 0.19 per cent.
Shares of Jet Airways rallied by 4 per cent after the airline reported a record profit of Rs 467.11 crore for the quarter ended December 31, on the back of lower input costs.
after Finance Minister Arun Jaitley last Saturday said an expert group will be constituted to consider a proposal for their merger.
Pramit Brahmbhatt of Veracity Financial Services said, "On the sectoral front, it was a mix trading session where banking and financial and IT stocks were on the losing side while metal, pharma and realty stocks gained."
The market breadth turned negative as 1,329 shares ended lower, 1,318 closed higher while 144 ruled steady.
The total turnover rose to Rs 4,898.05 crore, from Rs 3,249.13 crore last Friday.