The South Pole has shown the same, relentless upward trend in carbon dioxide (CO2) as the rest of world, but its remote location means it is the last to register the impacts of increasing emissions from fossil fuel consumption, the primary driver of greenhouse gas pollution, researchers said.
"The far southern hemisphere was the last place on earth where CO2 had not yet reached this mark," said Pieter Tans, the lead scientist of US National Oceanic and Atmospheric Administration (NOAA)'s Global Greenhouse Gas Reference Network.
Over the course of the year, CO2 levels rise during fall and winter and decline during the Northern Hemisphere's summer as terrestrial plants consume CO2 during photosynthesis.
However, plants only capture a fraction of annual CO2 emissions, so for every year since observations began in 1958, there has been more CO2 in the atmosphere than the year before.
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Last year's global CO2 average reached 399 ppm, meaning that the global average in 2016 will almost certainly surpass 400 ppm. The only question is whether the lowest month for 2016 will also remain above 400 metres, researchers said.
Part of last year's jump was attributable to El Nino, the cyclical Pacific Ocean warming that produces extreme weather across the globe, causing terrestrial ecosystems to lose stored CO2 through wildfire, drought and heat waves.
Last year was the fourth consecutive year that CO2 grew more than 2 ppm - which set another record. This year promises to be the fifth.
"Since emissions from fossil fuel burning have been at a record high during the last several years, the rate of CO2 increase has also been at a record high. And we know some of it will remain in the atmosphere for thousands of years," he said.