The 65-year-old singer said he was impressed with the presenters voice when they sang together before, Female First.
"Yes I think I would, he's a pretty good singer actually James. I've sang with him before but not in a car. We'll see. My job is to surprise people. When I listen to music, I want to be surprised. When I compose music, I want to surprise people.
"When I choose music I want to present for a new album, I want to be surprised, so I think I may have done this. Music is an endless ocean you can swim in forever with no bottom and no edge so I'm still learning," Sting said.
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