The defections followed a US decision to give the rebels "military support" after Washington reviewed evidence showing the Syrian regime had used chemical weapons.
But Russia said the regime, which bombarded the outskirts of Damascus today, had no need to use chemical weapons because its forces were making steady advances on the ground.
The defection of 71 army officers and two policemen came over a period of 36 hours, the Turkish official told AFP.
Meanwhile, US President Barack Obama held talks on Syria with European leaders late on Friday, the White House said.
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The discussions with British Prime Minister David Cameron, French President Francois Hollande, Italian Prime Minister Enrico Letta and German Chancellor Angela Merkel came ahead of the G8 summit to be held in Northern Ireland next week.
"The five leaders discussed Syria, including the regime's use of chemical weapons against its own people, and ways to support a political transition to end the conflict," the White House said today.
On Thursday, Washington said it had evidence that the Syrian regime had used chemical weapons, including the nerve gas sarin, in attacks that killed up to 150 people.
It also said without giving details that the administration had decided to boost its support for the rebels seeking to overthrow President Bashar al-Assad, including "military support."
That decision, and the allegations of chemical weapons use by the regime, were criticised by Russia, which is a staunch Assad ally.
"The regime, as the opposition is saying out in the open, is enjoying military success on the ground," he told reporters during a joint press appearance with his Italian counterpart Emma Bonino.
"What sense is there for the regime to use chemical arms -- especially in such small amounts?" Lavrov asked.
He warned that it would be wrong for the US administration "to be sending signals" to the opposition that could jeopardise attempts to find a political solution to the Syrian conflict.