"I believe tomorrow we will take a decision" on whether or not to attend the UN-brokered negotiations, said one delegate from the Saudi-backed High Negotiations Committee.
"We will not be in Geneva tomorrow," said another opposition source.
The Committee was formed in December when the main Syrian political opposition and armed factions came together in Riyadh for an unprecedented bid at unity, after months of Saudi effort.
It insists that it is the sole permitted representative of Syria's opposition, despite objections from others.
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It had said it was waiting for UN "clarifications" after the UN issued invitations to other opposition figures.
But delegate Monzer Makhos told AFP that members "would not be there" in Geneva for the planned start of talks "as we have yet to make a decision".
The Committee wants assurances from the international community that it will move to end regime attacks on civilians and allow humanitarian aid.
The Riyadh discussions were to resume at 0600 GMT tomorrow, the delegate said.