Other big name acts lined up for the event include Ed Sheeran, Paolo Nutini, Lily Allen and Elbow, reported Daily Mirror.
"We have pulled together a line-up of huge depth with a variety of artists across many musical genres and 2014 is set to be another fantastic year in V Festival's 19-year history," V Festival director Bob Angus said.
Crowd-pleasing star Nile Rodgers and Brit Award winners Bastille, Sam Smith and Rudimental, will also be performing at the event.
In addition, the line-up will include Example, Kaiser Chiefs, Manic Street Preachers, The Human League and All Saints among others, who will perform on four stages across each site.