"The main objective of the talks we are planning to have is the de-escalation, to find real ways how to de-escalate the situation," said Yurii Klymenko, Kiev's ambassador to the United Nations in Geneva, location of Thursday's talks.
"Ukraine is not going to discuss at this meeting the internal issues of Ukraine," he told reporters.
Moscow has demanded that pro-Russian separatists take part in the meeting, which marks a new diplomatic effort to defuse tensions between Kiev's pro-Western government and Moscow that have caused the worst European security crisis in decades.
But Kiev, which blames Moscow for stoking strife, has rejected the idea of having specific representatives of the country's restless south and east at the table in Geneva.
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"We are not going to discuss the federalisation of Ukraine," said Klymenko.
"We strongly believe that regions of Ukraine have to have more freedom, and now the government of Ukraine is very much committed to decentralise, to give more powers to the regions, but we are not talking about federalisation," he added.
Russian Foreign Minister Sergei Lavrov today warned Kiev against using force to quell the separatists, saying such a "criminal" act would undermine the planned talks.
Klymenko hit back, defending Kiev's efforts to halt the separatists' takeover of public buildings.
"This anti-terrorist campaign is directed not against the people, it's directed first of all against the separatists who are provoking violence in my country," he said.
Klymenko said that Kiev planned at the Geneva meeting to deliver "vast and concrete evidence" of Moscow's misdeeds on Ukrainian soil.
He also questioned Moscow's commitment to dialogue.