Researchers at Massachusetts Institute of Technology in the US found that some cities, such as New York and Chicago, are laid out on a precise grid, like the atoms in a crystal.
While others such as Boston or London are arranged more chaotically, like the disordered atoms in a liquid or glass, they said.
They found that the "crystalline" cities had a far greater buildup of heat compared to their surroundings than did the "glass-like" ones.
The researchers noted that using mathematical models that were developed to analyse atomic structures in materials provides a useful tool, leading to a straightforward formula to describe the way a city's design would influence its heat-island effect.
"If you are planning a new section of Phoenix, you dont want to build on a grid, since it's already a very hot place. But somewhere in Canada, a mayor may say no, we'll choose to use the grid, to keep the city warmer," said Roland Pellenq from Massachusetts Institute of Technology.