Singh will be attending the meeting as External Affairs Minister Sushma Swaraj has not yet started foreign travel after her kidney transplant operation, Indian officials said.
Foreign Ministry spokesperson Lu Kang said today that Chinese Foreign Minister Wang Yi will chair the meeting that will take place here from June 18 to 19.
Lu was quoted by the state-run Xinhua News agency as saying that the meeting will also be attended by Russian Foreign Minister Sergey Lavrov, South African Foreign Minister Maite Nkoana-Mashabane, Brazilian Foreign Minister Aloysio Nunes and Singh.
Incidentally, this is first time Foreign Ministers meeting has been called ahead of the Summit by the host country.
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China took over the rotating presidency of the BRICS from India after last year's Goa Summit of the group of emerging countries.
The Ministers' meeting was regarded as significant from both the bilateral point of view for India as well as from this year's summit, the structure of which would be decided by the host country.
China also continues to maintain that there is no change in its stand on India's entry into the Nuclear Suppliers Group (NSG) as well as New Delhi's efforts to get Jaish-e-Mohammed (JeM) leader Masood Azhar banned by the UN.
Diplomatically, both the countries have been warming up after the BRF and the BRICS Foreign Ministers meeting and the NSA's meeting was expected to provide a platform for informal exchanges to move forward, officials said.
His proposals have not been taken up for discussion by both the countries.
Also, China was expected to outline its proposals for the BRICS summit, specially which are the countries it plans to invite.
At the Goa Summit, India invited heads of the members of BIMSTEC (Bay of Bengal Initiative for Multi-Sectoral Technical and Economic Cooperation).