The 44-year-old actress has worn Valentino many times in the past, most recently to the 2013 Oscars, where she stepped out of her comfort zone in a crimson, princess-style gown, reported the Huffington Post.
The 'Friends' star would not be the first celebrity to don Valentino for her big day. Earlier, Oscar-winning-actress Anne Hathaway famously wore a custom-made confection at her wedding to Adam Shulman.
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