The war of words escalated yesterday, the second day of a 48-hour general strike by Venezuelans angry over Maduro's plans for a Sunday vote to elect a new body to rewrite the constitution.
"The regime declared we can't demonstrate... We will respond with the TAKING OF VENEZUELA" through a protest on Friday, the opposition coalition, the Democratic Unity Roundtable, said on its Twitter account.
He called for immediate dialogue -- but signalled he was not backing down. Any talks, he said, should happen "before the election and installation of the Constituent Assembly" tasked with rewriting the constitution.
Earlier, he issued a decree warning anybody taking part in protests that "could disturb or affect" Sunday's vote risked five to 10 years in prison.
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Four months of violent protests have already left 108 people dead, according to prosecutors. Five of them -- including two minors -- died in protests during the two-day strike.
Demonstrations have intensified in recent days as the opposition seeks to thwart Maduro's plans and oust him through early elections.
International concern has mounted, with the United States, European Union, United Nations and most heavyweight Latin American nations urging Maduro to back down from his plan.
Some 70 per cent of Venezuelans oppose plans for the constituent assembly, according to polling firm Datanalisis.
The United States has responded to Maduro's intransigence by imposing economic sanctions on 13 current and former Venezuelan officials, freezing their US assets and forbidding US entities from doing business with them.
Maduro branded the US punishment "illegal, insolent and unprecedented."
It is pushing on with its own strategy of trying to force Maduro from power through early elections.
Skirmishes in the street between supporters of the opposition and the Maduro government have become commonplace.
Volleys of tear gas, rubber bullets and homemade bombs arced through the air in the capital during the strike.
Barricades made from debris littered the eastern part of the city, with signs reading "No more dictatorships!"
"What happens if they impose the constituent assembly? The crisis will worsen. Where does Maduro want to take the country? To a social explosion?" asked Henrique Capriles, an opposition leader.
Maduro accuses Washington of fomenting unrest against him, aided by the conservative opposition. He has increasingly relied on the Venezuelan military, which has repeatedly declared loyalty to him, to hold onto power.
US Treasury Secretary Steven Mnuchin, announcing America's sanctions on Wednesday, warned that any of the 545 members to be elected to Maduro's constituent assembly could also face US punishment.
Venezuela's opposition, bolstered by an unofficial vote on July 16 that saw a third of the electorate reject Maduro's plan, has called for a vote boycott.
The oil export-dependent economy will shrink 12 per cent this year, after a contraction of 18 percent last year, the International Monetary Fund said.
Inflation is projected to top 720 per cent.
Venezuela's currency reserves have dwindled to under USD 10 billion as the government keeps up debt repayments at the expense of imports to stave off a devastating default.
The country's isolation was being seen in the number of airlines cutting services to and from Venezuela.
Avianca, a major Colombian carrier, said yesterday it was ending flights immediately, moving forward a suspension originally announced for mid-August.
Currency controls have made it nearly impossible for foreign companies to operate in the country. A Venezuelan source said the government debt to airlines had reached USD 3.8 billion.
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