The incident took place around 8:30 PM in CRPF's Jharoda Kalan campus in South West Delhi.
The deceased has been identified as Anamika while the pillion rider, identified as constable Jyoti received minor injuries in the accident.
Police was informed about the accident by the authorities of CRPF Camp Hospital around 9 PM.
When a police team reached the hospital, they were told that the accident took place near VIP Hut in the CRPF campus.
Police has recovered the motorcycle from the spot, but no eyewitnesses were found. A case of rash driving and causing death by negligence has been registered at Baba Haridas Nagar police station and investigations are on, they said.