Marlohe, 33, will star alongside Ryan Gosling, Michael Fassbender and Natalie Portman.
The untitled movie revolves around two intersecting love triangles, obsession and betrayal, set against the music scene, the Hollywood Reporter said.
It stars Christian Bale, Cate Blanchett, Michael Fassbender, Ryan Gosling, Rooney Mara and Natalie Portman.
The details of Marlohe's character are not available but it is a big move for actress, who plays enigmatic Severine opposite Daniel Craig in 'Skyfall'.
A jinx is often associated with Bondgirls as most of the actresses who have appeared in the 007 series have failed to make a mark but there have been exceptions with stars like Teri Hatcher, Halle Berry, Diana Rigg and Kim Basinger doing well in Hollywood.