The Brazilian supermodel will appear in the French fashion house's advertising campaign, which is expected to be released on March 15, reported Femalefirst.
The 32-year-old, who gave birth to her and American footballer husband Tom Brady's second child, Vivian Lake Brady in December 2012, shot the campaign last spring with famed photographer Mario Testino.
The new make-up range provides a lightweight texture with a natural look.
Bundchen was previously the face of Max Factor's make-up range, signing a two-year deal worth USD 2.5 million with the cosmetics brand in 2008.
