The 23rd Bond film will premier on October 23 at The Royal Albert Hall and it will be attended by the film's helmer Sam Mendes and leading actors Craig, Judi Dench, Javier Bardem, Naomie Harris and Ben Whishaw.
This is Craig's third Bond film after "Casino Royale" and "Quantum of Solace".
The premier will benefit the charities that support former and serving members of the three intelligence agencies - the Secret Intelligence Service, the Security Service and GCHQ.
"We are thrilled His Royal Highness Prince Charles and The Duchess of Cornwall have agreed to attend the World Premiere of our latest James Bond film, and are pleased this event will help raise funds to support The Prince
