Scientists have developed a novel method to create dyed threads for clothes that change colour when they detect a variety of gases.
The researchers at Tufts University in the US demonstrated that the threads can be read visually, or even more precisely by use of a smartphone camera, to detect changes of colour due to analytes as low as 50 parts per million.
Woven into clothing, smart, gas-detecting threads could provide a reusable, washable, and affordable safety asset in medical, workplace, military and rescue environments, they said.
The study, published in the journal Scientific Reports, describes the fabrication method and its ability to extend to a wide range of dyes and detection of complex gas mixtures.
While not replacing the precision of electronic devices commonly used to detect volatile gases, incorporation of gas detection into textiles enables an equipment-free readout, without the need for specialised training, the researchers said.
Such an approach could make the technology accessible to a general workforce, or to low resource communities that can benefit from the information the textiles provide.
The study used a manganese-based dye, MnTPP, methyl red, and bromothymol blue to prove the concept.
MnTPP and bromothymol blue can detect ammonia while methyl red can detect hydrogen chloride -- gases commonly released from cleaning supplies, fertiliser and chemical and materials production.
A three-step process "traps" the dye in the thread. The thread is first dipped in the dye, then treated with acetic acid, which makes the surface coarser and swells the fibre, possibly allowing more binding interactions between the dye and tread.
Finally, the thread is treated with polydimethylsiloxane (PDMS), which creates a flexible, physical seal around the thread and dye, which also repels water and prevents dye from leaching during washing.
The PDMS is also gas permeable, allowing the analytes to reach the optical dyes.
"The dyes we used work in different ways, so we can detect gases with different chemistries," said Sameer Sonkusale, a professor at Tufts University.
"But since we are using a method that effectively traps the dye to the thread, rather than relying so much on binding chemistry, we have more flexibility to use dyes with a wide range of functional chemistries to detect different types of gases," he said.
The tested dyes changed colour in a way that is dependent and proportional to the concentration of the gas as measured using spectroscopic methods.
In between the precision of a spectrometer and the human eye is the possibility of using smart phones to read out and quantify the colour changes or interpret colour signatures using multiple threads and dyes.
"That would allow us to scale up the detection to measure many analytes at once, or to distinguish analytes with unique colorimetric signatures," said Sonkusale.
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